廖良生教授、蒋佐权教授在Angew. Chem. Int. Ed.上发表论文

题目：

Near-Infrared Electroluminescence beyond 800 nm with High Efficiency and Radiance from Anthracene Cored Emitters

作者：

You-Jun Yu¹, Yun Hu¹, Sheng-Yi Yang¹, Wei Luo¹, Yi Yuan¹, Chen-Chen Peng¹, Jin-Feng Liu¹, Aziz Khan¹, Zuo-Quan Jiang*¹, Liang-Sheng Liao*^1,2

单位：

¹Institute of Functional Nano and Soft Materials (FUNSOM), and Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, China.

²Institute of Organic Optoelectronics Jiangsu Industrial Technology Research Institute (JITRI) Wujiang, Suzhou, China.

摘要：

Derivatives based on anthryleno [1,2-b] pyrazine-2,3-dicarbonitrile (DCPA) are used as luminescent materials, to realize near-infrared (NIR) electroluminescence. By functionalizing DCPA with aromatic amine donors, two emitters named DCPA-TPA and DCPA-BBPA are designed and synthesized. Both molecules have large dipole moments due to the strong intramolecular charge transfer interactions between the amine donors and the DCPA acceptor. Thus, compared with doped films, the emission of neat films of DCPA-TPA and DCPA-BBPA can fully fall into the NIR region (>700 nm) with increasing surrounding polarity by increasing doping ratio. Moreover, the non-doped devices based on DCPA-TPA and DCPA-BBPA provide NIR emission with peaks at 838 and 916 nm, respectively. A maximum radiance of 20707 mW Sr^-1 m^-2 was realized for the further optimized device based on DCPA-TPA. This work provides a simple and efficient strategy of molecular design for developing   NIR emitting materials.

影响因子：

12.257

分区情况：

一区

链接：

https://doi.org/10.1002/anie.202006197