何乐教授课题组及其合作者在Adv. Mater.上发表论文

发布时间:2022-01-13访问量:19设置

题目:

Stabilization of Exposed Metal Nanocrystals in High-temperature Heterogeneous Catalysis

作者:

Zhijie Zhu1, Kai Feng2, Chaoran Li1,*, Rui Tang1, Mengqi Xiao1, Rui Song1, Di Yang1, Binhang Yan2,*, Le He1,*

单位:

1 Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University,Suzhou 215123, China

2 Department of Chemical Engineering, Tsinghua University, 100084, Beijing, PR China

摘要:

Colloidal metal nanocrystals with uniform sizes, shapes, compositions and architectures are ideal building blocks for constructing heterogeneous catalysts with well-defined characteristics towards the investigation of accurate structure-property relationships and better understanding of catalytic mechanism.  However, their applications in high-temperature heterogeneous catalysis are often restricted by the difficulty in maintaining the high metal dispersity and easy accessibility to active sites under harsh operating conditions.  Here, we propose a partial-oxide-coating strategy to stabilize metal nanocrystals against sintering and meanwhile enable an effective exposure of active sites.  As a proof-of-concept, we demonstrate controlled partial silica coating of colloidally prepared Pd0.82Ni0.18 nanocrystals with the size of 8 nanometers.  This partially coated catalyst exhibits excellent activity, selectivity and stability, outperforming its counterparts with fully coated and supported structures, in reverse water gas shift catalysis particularly at high operating temperatures.  Our study opens a new avenue for the exploration of colloidal metal nanocrystals in high-temperature heterogeneous catalysis.

影响因子:

27.398

分区情况:

一区

链接:

https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.202108727


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