李彦光教授课题组在ACS nano上发表论文

发布时间:2018-04-27访问量:10设置

题目:

Rational Synthesis and Assembly of Ni3S4 Nanorods for Enhanced Electrochemical Sodium-Ion Storage

作者:

Jun Deng,e Qiufang Gong,e Hualin Ye, Kun Feng, Junhua Zhou, Chenyang Zha, Jinghua Wu, Junmei Chen, Jun Zhong, and Yanguang Li

单位:

Institute of Functional Nano & Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nanoscience and Technology, Soochow University, 199 Ren-AiRoad, Suzhou 215123, China.

ethese authors contribute equally

摘要:

Even though advocated as the potential low-cost alternatives to current lithium-ion technology, the practical viability of sodium-ion batteries remains illusive and depends on the development of high-performance electrode materials. Very few candidates available at present can simultaneously meet the requirements on capacity, rate capability, and cycle life. Herein, we report a high-temperature solution method to prepare Ni3S4 nanorods with uniform sizes. These colloidal nanorods readily self-assemble side by side and form microsized superstructures, which unfortunately negates the nanoscale feature of individual nanorods. To this end, we further introduce two-dimensional graphene nanosheets as the spacer to interrupt nanorod self-assembly. Resultant composite presents a marked advantage toward electrochemical storage of Na+ ions. We demonstrate that in half-cells it exhibits large reversible specific capacity in excess of 600 mAh/g, high rate capability with >300 mAh/g retained at 4 A/g, and great cycle life at different current rates. This anode material can also be combined with the NASICON-type Na3V2(PO4)3 cathode   in full cells to enable large capacity and good cyclability.

影响因子:

13.942

分区情况:

一区

链接:

https://pubs.acs.org/doi/abs/10.1021/acsnano.7b08625


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