刘阳 教授

发布时间:2017-04-25访问量:152设置

教授 硕士生导师


研究领域:

以胶体化学为研究手段,以金属、半导体纳米材料及其复合结构为研究核心,致力于多功能、复合体系的设计与构筑,揭示其结构与催化、光电化学性质间的相互关系。利用复合体系的协同效应、能量传递来实现多级纳米结构的构筑与性能的仿生设计。研究目标瞄准太阳能利用、环境与新能源等领域。


主要成果和技术贡献:

1. 构筑一系列基于碳量子点/半导体纳米复合结构的高效光催化体系,如CQDs/TiO2CQDs/Cu2OCQDs/Fe2O3CQDs/SiO2等。

2. 利用电化学合成技术制备出直径小于4 nm的具有良好荧光特性的碳量子点,首次提出碳量子点的荧光上转换特性,并设计了基于碳量子点的复合催化剂体系(CQDs/TiO2),此复合体系可有效实现催化剂对太阳光全光谱的利用。该工作发表后,NPG Asia Materials“Nanomaterials: Energizing carbon dots”为题对该工作进行了亮点报道。

3. 首次提出并证实了聚苯胺纳米粒子作为有机催化剂的纳米尺寸效应。

4. 建立了一系列用于合成不同尺寸荧光碳纳米粒子的技术路线,如电化学法、水热法、超声法、微波法等。

5. 探索了用于合成包括ZnO纳米线、纳米棒、纳米带、纳米绒棒以及纳米花蕾等结构在内的一维ZnO的纳米阵列结构的有效实验方案。

6. 建立了用于合成具有多种中空结构的金属纳米材料的有效技术路线。

Science, Energy Environ. Sci., Angew. Chem. Int. Ed., Adv. Funct. Mater.Nanoscale, J. Phys. Chem. C, Chem. Eur. J, J. Mater. Chem., Chem. Commun.等国际权威杂志发表学术论文100余篇,或授权发明专利3项。担任J. Am. Chem. Soc., Small, Nanoscale, J. Mater. Chem.A,ACS Appl. Mater. Interface20多个国际学术杂志的审稿人。

  

承担项目情况:

1.国家自然科学基金面上项目:基于碳点的双效(ORR/OER)点催化剂设计(51572179),2016.01–2019.12,主持。

2.国家自然科学基金面上项目:C/ZnO(TiO2纳米复合体系的能量传递与光催化剂设计(21073127),2011.01–2013.12,主持。

3.苏州市科技计划项目(纳米技术专项):碳量子点/无机半导体纳米复合高效光催化剂的构筑与催化特性研究(ZXG2012028),2012.07-2015.06,主持。

4.江苏省高校自然科学研究项目:非金刚石型碳纳米粒子的荧光性质及生物成像(11KJB150015),2011.09–2013.12,主持。

5.国家自然科学基金青年基金项目:ZnO的一维纳米材料及量子点:合成、组装及光化学性质研究(20803008),2009.01–2011.12,主持。

  

招生:

欢迎有化学及化工、材料学、物理学和新能源等相关专业的本科生和硕士生报考,欢迎本科生来课题组学习和交流,同时欢迎博士生和博士后加盟。如有疑问请随时联系yangl@suda.edu.cn 0512-65880956

  

代表性论文:

1. Yan-Mei Yang, Juan Liu, Si-Jie Guo, Yang Liu,* and Zhen-Hui Kang*, Nickel Nanoparticle/Carbon Quantum Dot hybrid as Efficient Electrocatalyst for Hydrogen Evolution under Alkaline Condition, J. Mater. Chem. A 2015, 3(36), 18598-18604.

2. Man-Man Yang, Juan Liu, Xing Zhang, Shi Qiao, Hui Huang, Yang Liu,* and Zhen-Hui Kang*, C3N4-sensitized TiOnanotube arrays with enhanced visible-light photoelectrochemical performance, Phys. Chem. Chem. Phys.2015, 17(27), 17887-17893

3. Hao Li, Si-Jie Guo, Chuan-Xi Li, Hui Huang, Yang Liu,* and Zhen-Hui Kang*, Tuning laccase catalytic activity with phosphate functionalized carbon dots by visible light, ACS Appl Mater Interface2015, 7(18), 10004-10012.

4. Hao Li, Wei-Qian Kong, Juan Liu, Nai-Yun Liu, Hui Huang, Yang Liu,* and Zhen-Hui Kang,* Fluorescent N-doped carbon dots for both cellular imaging and high-sensitive catechol detection, Carbon2015, 91, 66-75.

5. Shun-Yan Zhao, Chuan-Xi Li, Juan Liu, Nai-Yun Liu, Shi Qiao, Yu-Zhi Han, Hui Huang,* Yang Liu,* Zhen-Hui Kang,* Carbon Quantum Dots/SnO2-Co3O4 Composite for Highly Efficient Electrochemical Water Oxidation, Carbon2015, 92, 64–73.

6. Hao Li, Juan Liu, Si-Jie Guo, Ya-Lin Zhang, Hui Huang,* Yang Liu and Zhen-Hui Kang, Carbon dots from PEG for highly sensitive detection of levodopa J. Mater. Chem. B 2015, 3(11), 2378-2387.

7. Yuzhi Han, Di Tang, Yanmei Yang, Chuanxi Li, Weiqian Kong, Hui Huang,* Yang Liu,* Zhenhui Kang,* Non-metal single/dual doped carbon quantum dots: a general flame synthetic method and electro-catalytic properties, Nanoscale2015, 7, 5955–5962.

8. Chang-Hai Liu, Rui-Hua Liu, Qi-Jun Sun, Jian-Bing Chang, Xu Gao, Yang Liu, Shuit-Tong Lee*, Zhen-Hui Kang*, Sui-Dong Wang*, Controlled synthesis and synergistic effect of graphene-supported PdAu bimetallic nanoparticles with tunable catalytic properties, Nanoscale2015, 7(14), 6356-6362.

9. Juan Liu, Yang Liu, Nai-Yun Liu, Yu-Zhi Han, Xing Zhang, Hui Huang, Yeshayahu Lifshitz,* Shuit-Tong Lee,* Jun Zhong, Zhen-Hui Kang,*Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway, Science2015, 347(6225), 970-974.

10. Bei-Bei Liu, Liang Bai, Xiao-Ling Lin, Kai-Xuan Li, Hui Huang,* Hai-Liang Hu,* Yang Liu,*Zhen-Hui Kang, Crystal engineering towards the luminescence property trimming of hybrid coordination polymers, CrystEngComm2015, 17(7), 1686-1692.

11. Wei-Qian Kong, H. Li, Rui-Hua Liu, Juan Liu, Si-Ji Guo, Yu-Zhi Han, Hui Huang, Yang Liu,*Zhen-Hui Kang,* Size-dependent and Real-Time Effect of SiO2 Nanoparticles on a Single Living HeLa Cell Membrane Permeability, J. Mater. Chem. B2015, 3(7), 1198-1203.

12. Shun-Yan Zhao, Juan Liu, Chuan-Xi Li, Wen-Bin Ji, Yan-Mei Yang, Hui Huang, Yang Liu,*Zhen-Hui Kang,* Tunable-ternary (N, P, B)-doped Porous Nanocarbon and Their Catalytic Properties for Oxygen Reduction Reaction, ACS Appl Mater Interface2014, 6(24), 22297–22304.

13. Yan-Mei Yang, Juan Liu, Yu-Zhi Han, Hui Huang, Nai-Yun Liu, Yang Liu,*Zhen-Hui Kang,* Porous cobalt, nitrogen-codoped carbon nanostructures from carbon quantum dots and VB12 and their catalytic properties for oxygen reduction, Phys. Chem. Chem. Phys.2014, 16(46), 25350-25357.

14. Man-Man Yang, H. Li, Juan Liu, Wei-Qian Kong, Shun-Yan Zhao, Chuan-Xi Li, Hui Huang, Yang Liu,*Zhen-Hui Kang,* Convenient and sensitive detection of norfloxacin with fluorescenct carbon dots, J. Mater. Chem. B2014, 2(45), 7964-7970.

15. Juan Liu, Yan-Mei Yang, Nai-Yun Liu, Yang Liu,* Hui Huang, Zhen-Hui Kang,* Total photocatalysis conversion from cyclohexaneto cyclohexanone by C3N4/Au nanocomposites, Green Chemistry2014, 16(10), 4559-4565.

16. Juan Liu, Heng-Chao Zhang, Di Tang, Xing Zhang, Li-Kai Yan, Yu-Zhi Han, Hui Huang, Yang Liu,*Zhen-Hui Kang,* Carbon Quantum Dot/Ag Nanoparticle/ Polyoxometalate Composites as Photocatalysts for Overall Water Splitting in Visible Light,ChemCatChem2014, 6(9), 2634-2641.

17. Nai-Yun Liu, Juan Liu, Wei-Qian Kong, H. Li, Hui Huang, Yang Liu,*Zhen-Hui Kang,* One-step green fabrication of N-doped carbon dots from C3N4 and their bioimaging application, J. Mater. Chem. B2014, 2(35), 5768-5774.

18. Hao Li, Wei-Qian Kong, Juan Liu, Man-Man Yang, Hui Huang, Yang Liu,*Zhen-Hui Kang,* Carbon dot for Photoswitching enzyme catalytic activity, J. Mater. Chem. B2014, 2(34), 5652-5658.

19. Wei-Qian Kong, Rui-Hua Liu, Hao Li, Juan Liu, Hui Huang,* Yang Liu,*Zhen-Hui Kang,* High-bright fluorescent carbon dots and their application in selective nucleoli staining, J. Mater. Chem. B2014, 2(34), 5077-5082.

20. Lei Zhou, Juan Liu, Wen-Bin Ji, Hui Huang, Hai-Liang Hu, Yang Liu,*Zhen-Hui Kang,* A nickel-modified polyoxometalate towards high efficient catalyst for hydrocarbon selective oxidation, J. Mater. Chem. A2014,2(32), 12686-12691.

21. Di Tang, Juan Liu, Xiu-Qin Wu, Rui-Hua Liu, Xiao Han, Yu-Zhi Han, Hui Huang, Yang Liu,*Zhen-Hui Kang,*Carbon Quantum Dot/NiFe Layered Double Hydroxide Composite as High Efficient Electrocatalyst for Water OxidationACS Appl. Mater. Interface2014,6(10), 7918-7925.

22. Xing Zhang, Yang Liu,*Zhen-Hui Kang,*3D Branched ZnO Nanowire Arrays Decorated with Plasmonic Au Nanoparticles for High-Performance Photoelectrochemical Water Splitting, ACS Appl. Mater. Interface2014, 6(6), 4480-4489.

23. Guang-Ju Zhang, Chuan-Xi Li, Juan Liu, Lei Zhou, Rui-Hua Liu, Xiao Han, Hui Huang, Hai-Liang Hu, Yang Liu,* Zhen-Hui Kang,* One-step conversion from metal-organic framework to Co3O4@N-doped carbon nanocomposites towards high efficient oxygen reduction catalyst J. Mater. Chem. A2014, 2(22), 8184-8189.

24. Lei Zhou, Juan Liu, Xing Zhang, Rui-Hua Liu, Hui Huang,* Yang Liu,*Zhen-Hui Kang,* Template-free fabrication of mesoporous carbons from carbon quantum dots and their catalytic application for hydrocarbon selective oxidation Nanoscale2014, 6(11), 5831-5837.

25. Wei-Qian Kong, Juan Liu, Rui-Hua Liu, Hao Li, Yang Liu,* Hui Huang, K. Y. Li, J. Liu, Shuit-Tong Lee, Zhen-Hui Kang,* Quantitative and Real-Time Effects of Carbon Quantum Dots on a Single Living HeLa Cell Membrane Permeability, Nanoscale2014, 6(10), 5116-5120.

26. Xing Zhang,Yang Liu,* Shuit-Tong Lee, S. H. Yang, Zhen-Hui Kang,* Coupling surface plasmon resonance of gold nanoparticles with slow-photon-effect of TiO2 photonic crystal for synergistically enhanced photoelectrochemical water splitting, Energy & Environmental Science2014, 7(4), 1409-1419.

27. Fang-Fang Zhao, Huan Dong, Bei-Bei Liu, Guang-Ju Zhang, Hui Huang, Hai-Liang Hu,* Yang Liu,*Zhen-Hui Kang,* Tuning Luminescence via Transition Metal-Directed Strategy in Coordination Polymers, CrystEngComm2014, 16, 4422-4430.

28. Yu-Zhi Han, Hui Huang, Heng-Chao Zhang, Yang Liu,* Xiao Han, Rui-Hua Liu, Hai-Tao Li, Zhen-Hui Kang,* Carbon Quantum Dots with Photoenhanced Hydrogen-BondCatalytic Activity in Aldol Condensations, ACS Catalysis2014, 4(3), 781-787.

29. Rui-Hua Liu, Hui Huang, Hai-Tao Li, Yang Liu,* Jun Zhong, You-Yong Li, Shuo Zhang, Zhen-Hui Kang,* Metal Nanoparticle/Carbon Quantum Dot Composite as a Photocatalyst for High-Efficiency Cyclohexane Oxidation, ACS Catalysis2014, 4(1), 328-336.

30. Hai-Tao Li, Rui-Hua Liu, Wei-Qian Kong, Juan Liu, Yang Liu,* Lei Zhou, Xing Zhang, Shuit-Tong Lee, Zhen-Hui Kang,* Carbon Quantum Dots with Photo-generated Proton Property as Efficient Visible Light Controlled Acid Catalyst, Nanoscale2014, 6(2), 867-873.


责任编辑:钟帅

返回原图
/