邵名望教授课题组和李艳青教授课题组合作在Advanced Functional Materials上发表文章

题目：

Rh-MoS₂ Nanocomposite Catalysts with Pt-Like Activity for Hydrogen Evolution Reaction

作者：

Yafei Cheng, Shunkai Lu, Fan Liao, Liangbin Liu, Yanqing Li,* and Mingwang Shao*

单位：

Institute of Functional Nano and Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-based Functional Materials and Devices, Soochow University, Suzhou, Jiangsu 215123, P. R. China

摘要：

High overpotentials and low efficiency are two main factors that restrict the practical application for MoS₂, the most promising candidate for hydrogen evolution catalysis. Here, Rh-MoS₂  nanocomposites, the addition of a small amount of Rh (5.2 wt%), exhibit the superior electrochemical hydrogen evolution performance with low overpotentials, small Tafel slope (24 mV dec⁻¹), and long term of stability. Experimental results reveal that 5.2 wt% Rh-MoS₂ nanocomposite, even exceeding the commercial 20 wt% Pt/C when the potential is less than −0.18 V, exhibits an excellent mass activity of 13.87 A mg metal⁻¹ at −0.25 V, four times as large as that of the commercial 20 wt% Pt/C catalyst. The hydrogen yield of 5.2 wt% Rh-MoS₂ nanocomposite is 26.3% larger than that of the commercial 20 wt% Pt/C at the potential of −0.25 V. The dramatically improved electrocatalytic performance of Rh-MoS₂ nanocomposites may be attributed to the hydrogen spillover from Rh to MoS₂.

影响因子：

12.124

分区情况：

1区

链接：

http://onlinelibrary.wiley.com/doi/10.1002/adfm.201700359/full