王照奎教授课题组在Angew. Chem. Int. Ed.上发表论文

题目：

Dual-Stage Reduction Strategy of Tin Perovskite Enables High Performance Photovoltaics

作者：

Yu-Tong Yang , Fan Hu, Tian-Yu Teng, Chun-Hao Chen, Jing Chen, Namatullah Nizamani, Kai-Li Wang, Yu Xia, Lei Huang, and Zhao-Kui Wang*

单位：

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China.

摘要：

The rapid oxidation of Sn²⁺ in tin-based perovskite solar cells (TPSCs) restricts their efficiency and stability have been main bottleneck towards further development. This study developed a novel strategy which utilizes thiosulfate ions (S₂O₃^2-) in the precursor solution to enable a dual-stage reduction process. In the solution stage, thiosulfate acted as an efficacious reducing agent to reduce Sn⁴⁺ to Sn²⁺, meanwhile, its oxidation products were able to reduce I₂ to I^- during the film stage. This dual reduction ability effectively inhibited the oxidation of Sn²⁺ and passivated defects, further promising an excellent stability of the perovskite devices. As a result, thiosulfate-incorporated devices achieved a high efficiency of 14.78% with open-circuit voltage reaching 0.96 V. The stability of the optimized devices achieved a remarkable improvement, maintaining 90% of their initial efficiencies after 628 hours at maximum-power point (MPP). The findings provid research insights and experimental data support for the sustained dynamic reduction in TPSCs.

影响因子：

16.1

分区情况：

一区

链接：

https://doi.org/10.1002/anie.202415681

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